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179701 Aldrich

Triethylborane solution

1.0 M in THF

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
concentration   1.0 M in THF
density   0.865 g/mL at 25 °C

Description

Packaging

100, 800 mL in Sure/Seal™

Application

Catalyst for:
• Allylation of aldehydes
• Decarboxylative C-C bond cleavage reactions
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations
• Regioselective hydroxyalkylation of unsaturated oxime ethers

Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes

Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 3399BC 4.3(3) / PGII
WGK Germany 
1
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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