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180211 Aldrich

Borane tert-butylamine complex

powder, 97%

Synonym: tert-Butylamine borane, NSC 114045, Trihydro(2-methyl-2-propanamine) boron

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   GKFJEDWZQZKYHV-UHFFFAOYSA-N
assay   97%
form   powder
mp   98-100 °C (dec.)(lit.)

Description

Packaging

25, 100 g in glass bottle

Application

Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:
• copper (I) oxide nanoparticles
• diphosphine-protected gold nanocluster
• 4-acetoxycinnamyl alcohols

Reactant involved in:
• Non-destructive analyses and conservation treatments of Indian drawings
• Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes
• The formation of σ-borane complexes
• Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins
• Photochemical hydroboration and oxidation of single-walled carbon nanotubes

General description

Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
RTECS 
EO3900000

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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