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188913 Aldrich

Catecholborane

98%

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Properties

Related Categories Boranes, Boronic Acids and Derivatives, Borylation Reagents, Chemical Synthesis, Organometallic Reagents,
InChI Key   CENMEJUYOOMFFZ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.507(lit.)
bp   50 °C/50 mmHg(lit.)
mp   12 °C(lit.)
density   1.125 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Application

A monofunctional hydroborating agent which reduces β-hydroxyketones to 1,3-diols. Effects conjugate reduction of α,β-enones.

Used to prepare B-alkylcatecholboranes which were used, in turn, to generate alkyl radicals forming aryl ethers from quinones. Employed in a preparation of C2-symmetric boron complexes from methylenebis(oxazolines) used for enantioselective reduction of ketones.

Packaging

25, 100 g in Sure/Seal™

Legal Information

Made under U.S. Pat. No. 6,204,405.

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN2924 - class 3 - PG 2 - forbidden air - acidic - Flammable liquids, corrosive, n.o.s., HI: all
WGK Germany 
3
Flash Point(F) 
35.6 °F
Flash Point(C) 
2 °C
Protocols & Articles

Articles

Ir(I)-Catalyzed C–H Borylation

Arylboronic acids and esters are invaluable tools for the chemical community. These powerful reagents are used for a variety of transformations, most notably the Suzuki-Miyaura cross-coupling reactio...
Josephine Nakhla
Chemfiles Volume 11 Article 1
Keywords: Catalysis, Coupling reactions, Cross couplings, Infrared spectroscopy, Methods, Tools

Peer-Reviewed Papers
15

References

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