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189006 Aldrich

(+)-3-(Trifluoroacetyl)camphor

98%

Synonym: 3-(Trifluoroacetyl)-D-camphor

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks More...
InChI Key   ISLOIHOAZDSEAJ-XGLFCGLISA-N
assay   98%
optical activity   [α]19/D +148°, c = 2.3 in methylene chloride
refractive index   n20/D 1.451(lit.)
bp   100-101 °C/16 mmHg(lit.)
density   1.172 g/mL at 25 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

(+)-3-(Trifluoroacetyl)camphor reacts with suitable chiral ketone precursors to generate chiral dioxiranes in situ, which can catalyse the direct asymmetric epoxidation of unfunctionalized olefins.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
WGK Germany 
3
Flash Point(F) 
179.6 °F
Flash Point(C) 
82 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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