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193666 Aldrich

Chloropentafluorobenzene

99%

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Properties

Related Categories Aryl, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis,
InChI Key   KGCDGLXSBHJAHZ-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.424(lit.)
bp   122-123 °C/750 mmHg(lit.)
density   1.568 g/mL at 25 °C(lit.)

Description

Packaging

25 g in glass bottle

Application

Chloropentafluorobenzene has been used in the preparation of:
• 1,2-difluoro-1,2-bis-(pentafluorophenyl)dichlorane via fluorination with elemental fluorine at 128°C
• 5-chloro-1-(difluorochloro)-2,3,4,5,6,6-hexafluoro-1,3-cyclohexadiene via reaction with chlorine trifluoride at −78°C

General description

Reaction between chloropentafluorobenzene and strong N-bases in polar aprotic solvents and in the presence of water has been investigated. Chloropentafluorobenzene on reaction with ammonia yields 4-chloro-2,3,5,6-tetrafluoroaniline and 2-chloro-3,4,5,6-tetrafluoroaniline.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
2
RTECS 
CZ1225500
Protocols & Articles
Peer-Reviewed Papers
15

References

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