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193801 Aldrich

4,4′-Di-tert-butylbiphenyl

99%

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Properties

Related Categories Arenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
InChI Key   CDKCEZNPAYWORX-UHFFFAOYSA-N
assay   99%
bp   190-192 °C/13 mmHg(lit.)
mp   126-130 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

Application

4,4′-Di-tert-butylbiphenyl was used in production of homoallylic amine derivatives. It was also used in the preparation of lithium di-tert-butylbiphenylide, a radical anion, superior to sodium or lithium naphthalenides for metalation reactions.

General description

4,4′-Di-tert-butylbiphenyl along with lithium catalyzes:
• reaction of chloromethyl ethyl ether and different carbonyl compounds to yield corresponding hydroxyethers
• reductive opening of N-phenylazetidine

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
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