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193992 Aldrich

N,N-Dimethyl-p-phenylenediamine

97%

Synonym: 4-(Dimethylamino)aniline, 4-Amino-N,N-dimethylaniline, N,N-Dimethyl-1,4-phenylenediamine, DMPPDA

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Properties

Related Categories Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines More...
assay   97%
bp   262 °C(lit.)
mp   34-36 °C(lit.)

Description

Packaging

5, 100, 500 g in glass bottle

Price and Availability

Suggested Laboratory Gloves


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<I>N</I>,<I>N</I>-Dimethyl-<I>p</I>-phenylenediamine

for spectrophotometric det. of SO42-, S2-, ≥97.0%

<I>N</I>,<I>N</I>-Dimethyl-<I>p</I>-phenylenediamine

technical, ≥95.0% (GC)

Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
T
Risk Statements (Europe) 
Safety Statements (Europe) 
28-45
RIDADR 
UN 2811 6.1 / PGII
WGK Germany 
3
RTECS 
ST0874000
Flash Point(F) 
195.8 °F
Flash Point(C) 
91 °C

Protocols & Articles

Peer-Reviewed Papers

References

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Degradation and detoxification of acid orange 52 by Pseudomonas putida mt-2: a laboratory study. Mansour HB, Ghedira K, Barillier D, et al. Environ. Sci. Pollut. Res. Int. 18(9), 1527-35, (2011)

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A direct continuous spectrophotometric assay for transglutaminase activity. de Macédo, P., et al. Anal. Biochem. 285, 16-20, (2000)

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Method for measuring antioxidant activity and its application to monitoring the antioxidant capacity of wines. Fogliano V, Verde V, Randazzo G, et al. J. Agric. Food Chem. 47(3), 1035-40, (1999)

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Decolourization and biodegradation of N,N'-dimethyl-p-phenylenediamine by Klebsiella pneumoniae RS-13 and Acetobacter liquefaciens S-1. Wong PK and Yuen PY J. Appl. Microbiol. 85(1), 79-87, (1998)

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Melanoidins exert a weak antiradical activity in watery fluids. Morales FJ and Babbel MB J. Agric. Food Chem. 50(16), 4657-61, (2002)

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Antiradical efficiency of Maillard reaction mixtures in a hydrophilic media. Morales FJ and Babbel MB J. Agric. Food Chem. 50(10), 2788-92, (2002)

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Continuous spectrophotometric assays for dopamine beta-monooxygenase based on two novel electron donors: N,N-dimethyl-1,4-phenylenediamine and 2-aminoascorbic acid. Wimalasena K and Wimalasena DS Anal. Biochem. 197(2), 353-61, (1991)

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The acute phase protein ceruloplasmin as a non-invasive marker of pseudopregnancy, pregnancy, and pregnancy loss in the giant panda. Willis EL PLoS ONE 6(7), e21159, (2011)

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Enhanced symbiotic performance by Rhizobium tropici glycogen synthase mutants. Marroquí S, Zorreguieta A, Santamaría C, et al. J. Bacteriol. 183(3), 854-64, (2001)

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Reactions of the Wurster's red radical cation with hemoglobin and glutathione during the cooxidation of N,N-dimethyl-p-phenylenediamine [correction of phenlenediamine] and oxyhemoglobin in human red cells. Störle C and Eyer P Chem. Biol. Interact. 83(3), 271-91, (1992)

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Ceruloplasmin releases pH-induced inhibition of cell proliferation stimulated by growth factors. Alcaín FJ and Löw H Redox Rep. 3(5-6), 287-93, (1997)

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NN-dimethyl-1,4-phenylenediamine as an alternative reductant for peptidylglycine alpha-amidating mono-oxygenase catalysis. Li C, Oldham CD, and May SW Biochem. J. 300 ( Pt 1), 31-6, (1994)

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Use of N,N-dimethyl-p-phenylenediamine to evaluate the oxidative status of human plasma. Verde V, Fogliano V, Ritieni A, et al. Free Radic. Res. 36(8), 869-73, (2002)

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Heterogeneity of sulfated microdomains within basement membranes of pulmonary airway epithelium. Khosla J, Correa MT, and Sannes PL Am. J. Respir. Cell. Mol. Biol. 10(4), 462-9, (1994)

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Conformational analysis of the electron-transfer kinetics across oligoproline peptides using N,N-dimethyl-1,4-benzenediamine donors and pyrene-1-sulfonyl acceptors. Issa JB, Salameh AS, Castner EW, et al. J. Phys. Chem. B 111(24), 6878-86, (2007)

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Validation of a micromethod for determining oxidized and reduced vitamin C in plasma by HPLC-fluorescence. Tessier F, Birlouez-Aragon I, Tjani C, et al. Int. J. Vitam. Nutr. Res. 66(2), 166-70, (1996)

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Spectrophotometric flow injection monitoring of sulfide during sugar fermentation. Silva CR, Barros VA, Basso LC, et al. Talanta 85(3), 1703-5, (2011)

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Reduction of dopamine beta-monooxygenase. A unified model for apparent negative cooperativity and fumarate activation. Wimalasena K, Dharmasena S, Wimalasena DS, et al. J. Biol. Chem. 271(42), 26032-43, (1996)

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Purification and characterization of laccase II of Aspergillus nidulans. Scherer M and Fischer R Arch. Microbiol. 170(2), 78-84, (1998)

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Sequential determination of trace amounts of iron and copper in water samples by flow injection analysis with catalytic spectrophotometric detection. Lunvongsa S, Tsuboi T, and Motomizu S Anal. Sci. 22(1), 169-72, (2006)

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Theoretical studies on the dimerization of substituted paraphenylenediamine radical cations. Punyain K, Kelterer AM, and Grampp G Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 83(1), 368-78, (2011)

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Purification and characterization of a novel laccase from the mushroom Pleurotus nebrodensis. Tian GT, Zhang GQ, Wang HX, et al. Acta Biochim. Pol. 59(3), 407-12, (2012)

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Assessment of antioxidative activity of lipid- and water-soluble vitamins in human whole blood. Comparative analysis between a biological test and chemical methods. Lesgards JF, Lehucher-Michel MP, Vidal N, et al. Int. J. Vitam. Nutr. Res. 75(1), 11-8, (2005)

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[Study on the oxidative coupling of p-amino-N,N-dimethylaniline with 1-amino-8-naphthol-3,6-disulfonic acid and its application]. Huang XY and Chen H Guang Pu Xue Yu Guang Pu Fen Xi 22(4), 627-30, (2002)

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Yeast alcohol dehydrogenase catalyzed reduction of p-nitroso-N, N-dimethylaniline by NADH. Leskovac V, Trivic S, and Anderson BM Ital. J. Biochem. 45(1), 9-18, (1996)

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Simple colorimetric method for determination of peroxide. Yalçin AS, Haklar G, and Emerk K Clin. Chem. 39(12), 2534-5, (1993)

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Merck 14,3254

Beil. 13,IV,106

Aldrich MSDS 1, 792:D / Corp MSDS 1 (1), 1405:A / FT-IR 2 (2), 2105:A / FT-IR 1 (1), 1242:D / FT-NMR 1 (2), 543:B / IR-Spectra (3), 743:C / RegBook 1 (1), 1433:F / Sax 6, 1189 / Sigma FT-IR 1 (2), 508:C / Structure Index 1, 223:B:8 / Vapor Phase 3, 1155:C

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