Bromotrimethylsilane 97%

Properties

Related Categories	Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents More...
assay	97%
contains	copper as stabilizer
refractive index	n20/D 1.424(lit.)
bp	79 °C(lit.)
density	1.16 g/mL at 25 °C(lit.)

Description

Application

Used with InCl₃ to catalyze the direct allylation of a variety of alcohols with allyltrimethylsilane.¹

Packaging

25, 100 g in Sure/Seal™

5 g in glass bottle

Price and Availability

Related Papers

1. Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3. J. Org. Chem. 71, 8516, (2006)

Documents

Certificate of Analysis

Certificate of Origin

ChemFiles Vol 7 No 3 (1 MB )

FT-IR Condensed Phase

FT-IR Raman

Pressure-Temperature Nomograph

Safety Information

Symbol	GHS02, GHS05
Signal word	Danger
Hazard statements	H226-H314
Precautionary statements	P280-P305 + P351 + P338-P310
Supplemental Hazard Statements	Reacts violently with water.
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes (Europe)	C
Risk Statements (Europe)	10-14-34
Safety Statements (Europe)	16-26-36/37/39-45
RIDADR	UN 2920 8/PG 2
WGK Germany	3
Flash Point(F)	77 °F
Flash Point(C)	25 °C

Technical information & documentation associated with this product is available in the Safety & Documentation tab.

Articles

Activating Reagents and Protecting Groups

The use of activating agents and protecting groups in organic synthesis is necessary to prevent unwanted side reactions from occurring when using other common reagents such as oxidizing or reducing a...
Chemfiles Volume 1 Article 3
Keywords: Organic synthesis

Papers

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1. Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3. J. Org. Chem. 71, 8516, (2006)

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J. Chem. Soc., Perkin Trans. II, 263, (1991)

Phosphorus-containing inhibitors of HMG-CoA reductase. 2. Synthesis and biological activities of a series of substituted pyridines containing a hydroxyphosphinyl moiety. J. Med. Chem. 34, 2804, (1991)

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Tetrahedron Lett. 34, 7713, (1993)

Aldrichimica Acta 14, 31, (1981)

Beil. 4,IV,4008

Fieser 9,73 / Fieser 10,59 / Fieser 12,79 / Fieser 15,51 / Fieser 16,50

Aldrich MSDS 1, 294:A / Corp MSDS 1 (1), 588:C / FT-IR 2 (3), 4349:D / FT-IR 1 (2), 1103:A / IR-Spectra (3), 1540:D / NMR-Reference 2 (2), 983:C / RegBook 1 (2), 2957:H / Sigma FT-IR 1 (2), 975:C / Structure Index 1, 468:B:3 / Vapor Phase 3, 1630:A