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195413 Aldrich

Methacrylonitrile

99%

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Properties

Related Categories Acrylic Monomers, Acrylonitrile, Materials Science, Monomers, Polymer Science More...
vapor pressure   64 mmHg ( 20 °C)
assay   99%
contains   50 ppm monomethyl ether hydroquinone as inhibitor
refractive index   n20/D 1.400(lit.)
bp   90-92 °C(lit.)
mp   −35.8 °C(lit.)
density   0.8 g/mL at 25 °C(lit.)

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Methacrylonitrile-d<SUB>5</SUB>

contains monomethyl ether hydroquinone (as stabilizer), 97 atom % D, 97% (CP)

Poly(acrylonitrile-<I>co</I>-methyl acrylate)

acrylonitrile ~94 wt. %

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3079 6.1(3) / PGI
WGK Germany 
1
RTECS 
UD1400000
Flash Point(F) 
53.6 °F
Flash Point(C) 
12 °C

Protocols & Articles

Peer-Reviewed Papers

References

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Effect of caffeine and alcohol on the toxicity and metabolism of methacrylonitrile in male Sprague-Dawley rats. Farooqui MY, Trevino M, and Garcia I Res. Commun. Mol. Pathol. Pharmacol. 120-121(1-6), 79-92, (2007)

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Effect of methacrylonitrile on membrane bound enzymes of rat brain. Unnisa AZ and Devaraj SN Indian J. Physiol. Pharmacol. 51(4), 405-9, (2007)

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NTP technical report on the toxicity studies of methacrylonitrile (CAS No. 126-98-7). Administered by gavage to F344/N rats and B6C3F1 mice. Ghanayem BI Toxic. Rep. Ser. (47), 1-56, A1-E6, (2000)

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Toxicology and carcinogenesis studies of methacrylonitrile (CAS No. 126-98-7) in F344/N rats and B6C3F1 mice (gavage studies). Natl. Toxicol. Program Tech. Rep. Ser. (497), 1-225, (2001)

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Toxicology of methacrylonitrile. Farooqui MY and Mumtaz MM Toxicology 65(3), 239-50, (1991)

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Cloning and functional expression of a nitrile hydratase (NHase) from Rhodococcus equi TG328-2 in Escherichia coli, its purification and biochemical characterisation. Rzeznicka K, Schätzle S, Böttcher D, et al. Appl. Microbiol. Biotechnol. 85(5), 1417-25, (2010)

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Relative neurotoxicological properties of five unsaturated aliphatic nitriles in rats. Gagnaire F, Marignac B, and Bonnet P J. Appl. Toxicol. 18(1), 25-31, (1998)

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Comparative developmental toxicities of aliphatic nitriles: in vivo and in vitro observations. Saillenfait AM and Sabaté JP Toxicol. Appl. Pharmacol. 163(2), 149-63, (2000)

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Comparative disposition of acrylonitrile and methacrylonitrile: quantitative whole-body autoradiographic studies in rats. Ahmed AE, Jacob S, and Ghanayem BI Fundam. Appl. Toxicol. 33(1), 49-59, (1996)

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Role of cytochrome P-450 2E1 in methacrylonitrile metabolism and disposition. Ghanayem BI, Sanders JM, Chanas B, et al. J. Pharmacol. Exp. Ther. 289(2), 1054-9, (1999)

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Effect of methacrylonitrile on cytochrome P-450 2E1 (CYP2E1) expression in male F344 rats. Wang H, Chanas B, and Ghanayem BI J. Toxicol. Environ. Health A 65(7), 523-37, (2002)

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Comparative xenobiotic metabolism between Tg.AC and p53+/- genetically altered mice and their respective wild types. Sanders JM, Burka LT, Chanas B, et al. Toxicol. Sci. 61(1), 54-61, (2001)

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Comparative metabolism of methacrylonitrile and acrylonitrile to cyanide using cytochrome P4502E1 and microsomal epoxide hydrolase-null mice. El Hadri L, Chanas B, and Ghanayem BI Toxicol. Appl. Pharmacol. 205(2), 116-25, (2005)

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Investigation of methacrylonitrile metabolism and the metabolic basis for the differences in its toxicity in rats and mice. Ghanayem BI, Sanchez IM, and Burka LT J. Pharmacol. Exp. Ther. 269(2), 581-8, (1994)

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Directed organic grafting on locally doped silicon substrates. Charlier J, Baraton L, Bureau C, et al. ChemPhysChem 6(1), 70-4, (2005)

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Excretion and identification of methacrylonitrile metabolites in the bile of male F344 rats. Ghanayem BI and Burka LT Drug Metab. Dispos. 24(4), 390-4, (1996)

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Characterization of the toxicity, mutagenicity, and carcinogenicity of methacrylonitrile in F344 Rats and B6C3F1 mice. Nyska A and Ghanayem BI Arch. Toxicol. 77(4), 233-42, (2003)

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Effects of the carcinogen, acrylonitrile, on forestomach cell proliferation and apoptosis in the rat: comparison with methacrylonitrile. Ghanayem BI, Elwell MR, and Eldridge SR Carcinogenesis 18(4), 675-80, (1997)

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Effect of dosing vehicle on the toxicity and metabolism of unsaturated aliphatic nitriles. Farooqui MY, Ybarra B, Piper J, et al. J. Appl. Toxicol. 15(5), 411-20, (1995)

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Evaluation of the developmental toxicity of methacrylonitrile in Sprague-Dawley rats and New Zealand white rabbits. George JD, Price CJ, Marr MC, et al. Fundam. Appl. Toxicol. 34(2), 249-59, (1996)

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Haematological and erythrocyte membrane changes induced by methacrylonitrile. Samikkannu T, Vasanthakumari V, and Devaraj SN Toxicol. Lett. 92(1), 15-20, (1997)

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Effects of aliphatic nitriles in micromass cultures of rat embryo limb bud cells. Saillenfait AM, Sabaté JP, and Gaspard C Toxicol. In Vitro 18(3), 311-8, (2004)

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Brain lipid peroxidation and antioxidant status after acute methacrylonitrile intoxication. Zeenath Unnisa A and Niranjali Devaraj S Drug Chem. Toxicol. 28(2), 187-95, (2005)

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Effect of methacrylonitrile on rat lung antioxidant enzymes. Samikkannu T and Devaraj SN Bull. Environ. Contam. Toxicol. 59(6), 894-900, (1997)

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Cytotoxicity of methacrylonitrile. Vasanthakumari V, Nalini R, Devaraj H, et al. Bull. Environ. Contam. Toxicol. 59(2), 274-8, (1997)

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Methacrylonitrile induced oxidative stress in rat liver. Vasanthakumari V, Devaraj SN, and Devaraj H Indian J. Biochem. Biophys. 34(6), 540-2, (1997)

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Merck 14,5942

Beil. 2,IV,1539

Aldrich MSDS 1, 1171:B / Corp MSDS 1 (2), 2226:C / FT-IR 2 (1), 1430:D / FT-IR 1 (1), 843:D / FT-NMR 1 (1), 1359:B / IR-Spectra (3), 504:B / NMR-Reference 2 (1), 701:C / RegBook 1 (1), 991:H / Sax 6, 1795 / Structure Index 1, 154:D:8 / Vapor Phase 3, 803:A

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