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196193 Aldrich

Red-Al® sodium bis(2-methoxyethoxy)aluminum hydride solution

≥60 wt. % in toluene

Synonym: SBAH, Sodium bis(2-methoxyethoxy)aluminum dihydride, Sodium dihydrido-bis(2-methoxyethoxy)aluminate

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Properties

Related Categories Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents
vapor pressure   21 mmHg ( 20 °C)
InChI Key   XJIQVZMZXHEYOY-UHFFFAOYSA-N
expl. lim.   7 %
concentration   ≥60 wt. % in toluene
density   1.036 g/mL at 25 °C

Description

Application

Employed in the efficient reduction of N-Boc amino acid secondary amides leading to chiral diamines.

Versatile reducing agent.

Packaging

50, 500 g in Sure/Seal™

Legal Information

Red-Al is a registered trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
2
Flash Point(F) 
39.2 °F
Flash Point(C) 
4 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Red-Al®

Red-Al®, or sodium bis(2-methoxyethoxy)aluminum dihydride (Vitride®, SMEAH), is a versatile reducing agent and a good substitute for LiAlH4 in many reactions. Red-Al® is nonpyrophoric, although still...
ChemFiles Volume 5 Article 9
Keywords: Asymmetric synthesis, Pauson-Khand Reaction, Reductions, Stille coupling

Peer-Reviewed Papers
15

References

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