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20023 Aldrich

O-tert-Butylhydroxylamine hydrochloride

≥99.0% (AT)

Synonym: 2-Aminooxy-2-methylpropane hydrochloride, O-(1,1-Dimethylethyl)hydroxylamine hydrochloride, tert-Butoxyamine hydrochloride

  • CAS Number 39684-28-1

  • Linear Formula (CH3)3CONH2 · HCl

  • Molecular Weight 125.60

  •  Beilstein Registry Number 3668106

  •  EC Number 254-590-1

  •  MDL number MFCD00043272

  •  PubChem Substance ID 24851352

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Properties

Related Categories Building Blocks, Chemical Synthesis, Hydroxylamines, Nitrogen Compounds, Organic Building Blocks More...
InChI Key   ZBDXGNXNXXPKJI-UHFFFAOYSA-N
assay   ≥99.0% (AT)
mp   ~155 °C (dec.)
solubility   H2O: soluble0.5 g/10 mL

Description

Packaging

1, 5 g in glass bottle

Application

O-tert-Butylhydroxylamine hydrochloride was used in the synthesis of N-methyl-O-tert-butylhydroxylamine hydrochloride. It was also used in the preparation of N-tert-butoxyamino acids as substrates for the unambiguous synthesis of N-hydroxy peptides.

Reactant involved in synthesis of biologically active molecules including:
• CGS 25966 derivatives for use as MMP inhibitors
• Imidazolidinedione derivatives for use as antimalarial treatments
• Pyrimidine ribonucleotide analogs as P2Y6 receptor agonists
• Rab proteins for isoprenylation and geranylgeranylation inhibition

Reactant involved in:
• Synthesis of N-(arylethyl)-O-tert-butylhydroxamates for use as Weinreb amide equivalents
• Double allylic alkylation of indole-2-hydroxamates
• SN2 substitution reactions at amide nitrogens
• Photocycloaddition to C=N bonds for synthesis of 1,3-diazepines

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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