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205249 Aldrich

Di-tert-butyl dicarbonate

ReagentPlus®, 99%

Synonym: Boc anhydride, Di-tert-butyl pyrocarbonate

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Properties

Related Categories Amine Protection, Chemical Biology, Chemical Reagents, Chemical Synthesis, Development Quantities for Research,
grade   ReagentPlus®
InChI Key   DYHSDKLCOJIUFX-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.409(lit.)
bp   56-57 °C/0.5 mmHg(lit.)
mp   23 °C(lit.)
density   0.95 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Application

Aminomethyl allene was prepared by reaction of Boc propargyl amine with formaldehyde, diisopropylamine and copper bromide as part of a series of Bovine Plasma Amine Oxidase inactivators.

Protection of alcohols as Boc derivatives via Lewis acid catalysis.

Reagent for the introduction of the Boc protecting group.

Reagent for the preparation of Boc protected amines.

Tris-Boc protected hydrazine allows preparation of Fmoc ester in a chromophoric reagent to monitor solid-phase aldehydes.

Packaging

1 kg in poly bottle

10 kg in composite drum

10, 50, 100 g in poly bottle

Warning

Hydrolyzes to t-butanol and CO2; causes internal pressure in bottle if exposed to moisture.

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2929 3(6.1) / PGII
WGK Germany 
3
RTECS 
HT0230000
Flash Point(F) 
98.6 °F
Flash Point(C) 
37 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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