206490 Aldrich

4-Ethynylanisole

97%

DOWNLOAD MSDS (PDF)

Synonym: 1-Ethynyl-4-methoxybenzene

Properties

Related Categories Alkynes, Building Blocks, Chemical Synthesis, Organic Building Blocks, Terminal More...
assay   97%
refractive index   n20/D 1.563(lit.)
bp   87-91 °C/11 mmHg(lit.)
mp   28-29 °C(lit.)
density   1.019 g/mL at 25 °C(lit.)

Description

Application

1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.1

Forms the corresponding propargyl aldehyde in good yield directly from DMF-dimethyl acetal without the need for making an acetylide salt.

Used together with an arylboronic acid and sodium azide in a copper-catalyzed, three-component synthesis of trisubstituted 1,2,4-triazoles. Employed in a study of a gold (III)-catalyzed hydroamination of alkynes leading to N-vinylindoles.

Packaging

1, 5 g in glass bottle

Price and Availability

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