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213306 Aldrich

Phenyl vinyl sulfoxide

95%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfoxides, Sulfur Compounds More...
InChI Key   MZMJHXFYLRTLQX-UHFFFAOYSA-N
assay   95%
refractive index   n20/D 1.585(lit.)
bp   93-95 °C/0.2 mmHg(lit.)
density   1.139 g/mL at 25 °C(lit.)
storage temp.   2-8°C
Gene Information   human ... LOC129293(129293)

Description

Packaging

5 g in glass bottle

General description

Phenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78°C in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions.

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
230 °F
Flash Point(C) 
110 °C
Protocols & Articles

Articles

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. Since the reaction involves the formation of a cyclic product vi...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Diels-Alder reaction, Immobilization

Peer-Reviewed Papers
15

References

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