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214949 Aldrich

Diisobutylaluminum hydride solution

1.0 M in cyclohexane

Synonym: DIBAL-H, DIBAL

  • CAS Number 1191-15-7

  • Linear Formula [(CH3)2CHCH2]2AlH

  • Molecular Weight 142.22

  •  Beilstein Registry Number 4123663

  •  MDL number MFCD00008928

  •  PubChem Substance ID 24852856

  •  eCl@ss 38120609

  • Popular Documents:  Bulletin (PDF)  

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Properties

Related Categories Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   AZWXAPCAJCYGIA-UHFFFAOYSA-N
concentration   1.0 M in cyclohexane
density   0.781 g/mL at 25 °C

Description

Application

Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.

Packaging

100, 800 mL in Sure/Seal™

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Precautionary statements 
RIDADR 
UN3399 - class 4.3 - PG 1 - EHS - Organometallic substance, liquid, water-reactive, flammable, HI: all (not BR)
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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