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217166 Aldrich

1-Methoxy-1,3-cyclohexadiene

technical grade, 65%

Synonym: 2,3-Dihydroanisole

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Properties

Related Categories Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds More...
grade   technical grade
InChI Key   LNRUJSUKKBJFOM-UHFFFAOYSA-N
assay   65%
refractive index   n20/D 1.488(lit.)
bp   40 °C/15 mmHg(lit.)
density   0.929 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

1-Methoxy-1,3-cyclohexadiene was used in the following studies:
• Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
• Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
• Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

General description

1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
80.6 °F
Flash Point(C) 
27 °C
Protocols & Articles

Articles

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. Since the reaction involves the formation of a cyclic product vi...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Diels-Alder reaction, Immobilization

Peer-Reviewed Papers
15

References

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