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218456 Aldrich

Ethyl 3-methyl-2-oxobutyrate

97%

Synonym: Ethyl dimethylpyruvate, Ketovaline ethyl ester

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Properties

Related Categories Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   CKTYYUQUWFEUCO-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.410(lit.)
bp   62 °C/11 mmHg(lit.)
density   0.989 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5 g in glass bottle

Application

Ethyl 3-methyl-2-oxobutyrate was used in the synthesis of (2SR,4SR)-5(S)-(N-Boc)-amino-6-cyclohexyl-4-hydoxy-2-isopropyl hexanoic acid.

General description

Ethyl 3-methyl-2-oxobutyrate reacts with a variety of allyl halides in the presence of indium to afford hydroxy unsaturated carbonyl compounds. Conformational behaviour of ethyl 3-methyl-2-oxobutyrate was investigated using solution FTIR in combination with ab initio calculations.

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Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Warning
Hazard statements 
RIDADR 
UN 3272 3 / PGIII
WGK Germany 
3
Flash Point(F) 
109.4 °F
Flash Point(C) 
43 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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