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220760 Aldrich

K-Selectride® solution

1.0 M potassium tri-sec-butylborohydride in THF

Synonym: Potassium tri-sec-butylborohydride solution

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Properties

Related Categories Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   NHEDTYWJTOUTDG-UHFFFAOYSA-N
concentration   1.0 M potassium tri-sec-butylborohydride in THF
density   0.913 g/mL at 25 °C

Description

Packaging

100, 800 mL in Sure/Seal™

Application

• Reducing reagent

Reactant for:
• Preparation of a PCP-pincer palladium hydride-K-Selectride complex
• Formation of P-H, P-C, and C-H bonds by hydride attack
• Stereoselective conjugate hydride reduction reactions

Stereoselective reducing agent for ketones. Hydride employed in regioselective reactions with transition metal ligands.

Legal Information

Selectride is a registered trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides., Reacts violently with water.
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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