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220809 Aldrich

Diethylzinc solution

15 wt. % in toluene

Synonym: Zincdiethyl

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Properties

Related Categories Chemical Synthesis, Dialkylzincs, Organometallic Reagents, Rieke and Organozinc Reagents
InChI Key   HQWPLXHWEZZGKY-UHFFFAOYSA-N
concentration   15 wt. % in toluene
density   0.915 g/mL at 25 °C

Description

Application

Employed together with CF3I in a Rh(I) catalyzed preparation of α-trifluoromethyl ketones from α,ß-unsaturated ketones. Promoter for the Wittig reaction of carbonyl compounds with dibromofluoroacetate and triphenylphosphine leading to α-fluroroacrylates. Ni catalyzed coupling with cyclic anhydrides.

Packaging

100, 800 g in Sure/Seal™

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN3399 - class 4.3 - PG 1 - EHS - Organometallic substance, liquid, water-reactive, flammable, HI: all (not BR)
WGK Germany 
3
Flash Point(F) 
44.6 °F
Flash Point(C) 
7 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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