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220817 Aldrich

2-(Trimethylsilyl)-1,3-dithiane

≥99%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks, S-Containing More...
InChI Key   BTTUMVHWIAXYPJ-UHFFFAOYSA-N
assay   ≥99%
refractive index   n20/D 1.533(lit.)
bp   54-55 °C/0.17 mmHg(lit.)
density   1.014 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

General description

2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalent.

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Safety & Documentation

Safety Information

RIDADR 
UN 3334
WGK Germany 
3
Flash Point(F) 
204.8 °F
Flash Point(C) 
96 °C
Protocols & Articles

Articles

Pd(0) EnCat™ 30NP

Pd(0) EnCat™ 30NP is a new microencapsulated hydrogenation catalyst offering key advantages over existing heterogeneous hydrogenation catalysts. Reductive transformations catalyzed by Pd(0) EnCat™ 30...
Aldrich ChemFiles 2006, 6.5, 13.
Keywords: Catalysis, Chemfiles, Hydrogenations

Peer-Reviewed Papers
15

References

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