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225460

Diironnonacarbonyl

98%, solid

Synonym(s):

Enneacarbonyldiiron, Iron enneacarbonyl, Nonacarbonyldiiron

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10 G

$113.00

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$512.00

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About This Item

Linear Formula:
Fe2(CO)9
CAS Number:
Molecular Weight:
363.78
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Product Name

Diironnonacarbonyl, 98%

assay

98%

form

solid

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O

InChI

1S/9CO.2Fe/c9*1-2;;

InChI key

JCXLZXJCZPKTBW-UHFFFAOYSA-N

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1 of 4

This Item
442658122459F3629
reaction suitability

core: iron, reagent type: catalyst

reaction suitability

core: iron, reagent type: catalyst

reaction suitability

core: iron, reagent type: catalyst

reaction suitability

core: iron, reagent type: catalyst

assay

98%

assay

97%

assay

98%

assay

≥99%

form

solid

form

solid

form

solid

form

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

Application

Reacts with phenylsilanes to give triply bridged diiron complexes.[1]

pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react 2

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Gree, R.
Synthesis, 341-341 (1989)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Crump, S. L.; Netka, J.; Rickborn, B.
The Journal of Organic Chemistry, 50, 2746-2746 (1985)
Robert Ponec et al.
Journal of computational chemistry, 29(9), 1387-1398 (2008-01-16)
The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anticipated for
Nu Xiao et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 603-608 (2006-01-13)
[{Micro-(phthalazine-N2:N3)}Fe2(micro-CO)(CO)6](1) reacts with organolithium reagents, RLi (R = CH3, C6H5, p-CH3C6H4, p-CH3OC6H4, p-CF3C6H4, p-C6H5C6H4), followed by treatment with Me3SiCl to give the novel diiron carbonyl complexes with a saturated N-N six-membered diazane ring ligand, [{C6H4CH(R)NNCH2}Fe2(C=O)(CO)6](2, R = CH3; 3, R

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