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225541 Aldrich

Diisopropyl azodicarboxylate

98%

Synonym: DIAD, Diisopropyl azodiformate

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Properties

Related Categories C-X Bond Formation (Non-Halogen), Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Mitsunobu,
InChI Key   VVWRJUBEIPHGQF-MDZDMXLPSA-N
assay   98%
impurities   ≤2% dichloromethane
refractive index   n20/D 1.420(lit.)
bp   75 °C/0.25 mmHg(lit.)
density   1.027 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

General description

Reacted with dioxaphosphorinanes and iron catalyst to generate rearranged phosphonium ylide products.

Packaging

25, 100, 500 g in poly bottle

5 g in glass bottle

Application

Reactant for preparation of:
• Chromenes resembling classical cannabinoids
• MK-3281 inhibitor of the hepatitis C virus NS5B polymerase
• Norbornene-based guanidine-rich polymers as mimcs of cell-penetrating peptides (CPP)
• Analogues of the Pseudomonas aeruginosa quorum-sensing molecule N-(3-Oxododecanoyl)-l-homoserine lactone with immunosuppressive but non-LasR-inducing properties
• Acceptor-donor-acceptor organic dyes for dye-sensitized solar cells
• 1,3-dioxane-2-carboxylic acid derivatives as PPARα/γ dual agonists
• Hydrazinophosphonates and hydrazinobisphosphonates via Mitsunobu and Arbuzov-type multicomponent application of the Morrison-Brunn-Huisgen betaine

Price and Availability


Laboratory Gloves

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3082 9 / PGIII
WGK Germany 
2
Flash Point(F) 
222.8 °F
Flash Point(C) 
106 °C
Protocols & Articles

Articles

Reagents for the Mitsunobu Reaction

One of the most powerful and widely used carboncarbon bond forming reactions in organic synthesis is the Mitsunobu reaction.1 The Mitsunobu reaction is also useful in the preparation of other moietie...
ChemFiles Volume 4 Article 2
Keywords: Mitsunobu Reaction, Organic synthesis

Peer-Reviewed Papers
15

References

Related Products

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Description

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775681 OTPP
08168 Timestrip Plus 8 °C

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