Synonym: TMS triflate, TMSOTf, Trifluoromethanesulfonic acid trimethylsilylester
CAS Number 27607-77-8
Linear Formula CF3SO3Si(CH3)3
Molecular Weight 222.26
Beilstein Registry Number 1868911
EC Number 248-565-4
MDL number MFCD00000406
PubChem Substance ID 24853510
Popular Documents: Specification Sheet (PDF) | RAMAN FTIR (PDF)
| Related Categories | Chemical Synthesis, Protecting and Derivatizing Reagents, Protection and Derivatization, Silicon-Based, Synthetic Reagents More... |
| assay | 99% |
| refractive index |
n |
| bp | 77 °C/80 mmHg(lit.) |
| density | 1.228 g/mL at 25 °C(lit.) |
Used to prepare difluoroboron triflate etherate a powerful Lewis acid especially in acetonitrile solvent.1 Reagent used in a Dieckmann-like cyclization of ester-imides and diesters.2
10, 50 g in ampule
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1. BF3.OEt2 and TMSOTf: A synergistic combination of Lewis acids. Chem. Commun. (Camb.), 4434, (2006)
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