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227730 Aldrich

Silver hexafluoroantimonate(V)





1, 5, 25 g in amber poly bottle


Generates stable cation radical salts1,2 and is used as an acidic catalyst in epoxide opening reactions3 and sulfenylation reactions.4 Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.5

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UN 3260 8 / PGII
WGK Germany 
Protocols & Articles


Fluorinating Reagents

The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinat...
Aldrich ChemFiles 2006, 6.2, 5.
Keywords: Fluorinations, Medicinal chemistry, Metathesis, Organic synthesis

Gold Catalysis

Gold catalysis is playing an increasing role in organic synthesis for the facile construction of complex architectures not readily accessed by standard methods. Gold catalysts mediate unique C–C, C–O...
Aldrich ChemFiles 2007, 7.5, 10.
Keywords: Catalysis, Chemfiles, Enyne rearrangements, Heterocycle formation, Isomerizations, Methods, Organic synthesis, Rearrangements

Related Content

Gold Catalyst in Chemical Synthesis

Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions

Peer-Reviewed Papers


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1. J. Org. Chem. 57, 6178, (1992)

2. Development of a Nazarov cyclization/Wagner-Meerwein rearrangement sequence for the stereoselective synthesis of spirocycles. J. Am. Chem. Soc. 129, 8060, (2007)


3. Chem. Lett., 1901, (1992)

4. Chem. Lett., 1, (1993)

5. Coordination Networks of 3,3'-Dicyanodiphenylacetylene and Silver(I) Salts: Structural Diversity through Changes in Ligand Conformation and Counterion. Hirsch, K.A. et al. Inorg. Chem. 36, 2960, (1997)


Fieser 5,577 / Fieser 7,320 / Fieser 11,467 / Fieser 17,17

Corp MSDS 1 (2), 3095:D / FT-IR 1 (2), 1239:D / FT-IR 2 (3), 4747:C / RegBook 1 (3), 3433:C

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