|Related Categories||Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Salts,|
1, 5, 25 g in amber poly
Generates stable cation radical salts1,2 and is used as an acidic catalyst in epoxide opening reactions3 and sulfenylation reactions.4 Used to prepare silver 3,3′-dicyanodiphenylacety
Certificate of Analysis
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xn,N|
|Risk Statements (Europe)||20/22-51/53|
|Safety Statements (Europe)||61|
|RIDADR||UN 3260 8 / PGII|
The importance of selectively fluorinating compounds in medicinal chemistry, biology, and organic synthesis is well appreciated and provides a major impetus to the discovery of new and mild fluorinat...
Aldrich ChemFiles 2006, 6.2, 5.
Keywords: Fluorinations, Medicinal chemistry, Metathesis, Organic synthesis
Gold catalysis is playing an increasing role in organic synthesis for the facile construction of complex architectures not readily accessed by standard methods. Gold catalysts mediate unique C–C, C–O...
Aldrich ChemFiles 2007, 7.5, 10.
Keywords: Catalysis, Enyne rearrangements, Heterocycle formation, Isomerizations, Organic synthesis, Rearrangements
Introduction Hashmi, Toste, Echavarren, and Haruta, among others, have fueled the advance of gold into the forefront of transition metal catalysis.1,2 Phosphine ligated gold(I) complexes have risen a...
Keywords: Asymmetric synthesis, Building blocks, Catalysis, Claisen rearrangement, Conia-Ene Reaction, Cyclizations, Cycloadditions, Cycloisomerizations, Cyclopropanations, Deprotonations, Ene reaction, Hydroaminations, Hydrogenations, Isomerizations, Ligands, Rautenstrauch rearrangements, Rearrangements, Reductions, Schmidt Reaction, Substitutions
1. J. Org. Chem. 57, 6178, (1992)
3. Chem. Lett., 1901, (1992)
4. Chem. Lett., 1, (1993)
5. Coordination Networks of 3,3'-Dicyanodiphenylacetylene and Silver(I) Salts: Structural Diversity through Changes in Ligand Conformation and Counterion. Hirsch, K.A. et al. Inorg. Chem. 36, 2960, (1997)
Fieser 5,577 / Fieser 7,320 / Fieser 11,467 / Fieser 17,17
Corp MSDS 1 (2), 3095:D / FT-IR 1 (2), 1239:D / FT-IR 2 (3), 4747:C / RegBook 1 (3), 3433:C
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