Synonym: Copper(I) bromide methyl sulfide complex, Cuprous bromide dimethyl sulfide complex, Cuprous bromide methyl sulfide complex
|Related Categories||Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Materials Science,|
|mp||132 °C (dec.)(lit.)|
Catalyst employed in the addition of Grignard reagents (alkyl, alkenyl, aryl) to fullerenes. This process adds 5 organic groups to fullerene and 3 groups to fullerene.1
10, 50 g in glass bottle
Certificate of Analysis
Certificate of Origin
|Precautionary statements||P261-P305 + P351 + P338|
|Personal Protective Equipment||dust mask type N95 (US), Eyeshields, Gloves|
|Hazard Codes (Europe)||Xi|
|Risk Statements (Europe)||36/37/38|
|Safety Statements (Europe)||26-36|
Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations
1. Organic Synth. 83, 80, (2006)
Rossiter, B. E. et al.B. E.; Swingle, N. M. Chem. Rev. 92, 771, (1992)
Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent. Robert, T.; Velder, J.; Schmalz, H.-G. Angew. Chem. Int. Ed. Engl. 47, 7718, (2008)
Fieser 6,225 / Fieser 8,117 / Fieser 10,104 / Fieser 15,100 / Fieser 16,96
Aldrich MSDS 1, 485:C / Corp MSDS 1 (1), 911:B / FT-IR 1 (2), 1248:B / FT-IR 2 (3), 4517:C / RegBook 1 (2), 3079:E / Structure Index 1, 488:C:4
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