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23070 Aldrich

(1-Chloroethyl)trimethylsilane

technical, ≥90% (GC)

  • CAS Number 7787-87-3

  • Empirical Formula (Hill Notation) C5H13ClSi

  • Molecular Weight 136.70

  •  Beilstein Registry Number 1732094

  •  EC Number 232-135-8

  •  MDL number MFCD00042611

  •  PubChem Substance ID 57648018

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Properties

Related Categories Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   UWJVDEZZIPJQRF-UHFFFAOYSA-N
grade   technical
assay   ≥90% (GC)
refractive index   n20/D 1.422
bp   116 °C(lit.)
density   0.864 g/mL at 20 °C(lit.)

Description

Other Notes

Treating this chlorosilane with sec-BuLi gives 1-chloro-1-trimethylsilylethyl lithium which reacts with aldehydes and ketones to form methyl ketones via an intermediate α,β-epoxysilane.; Used in an efficient synthesis of R(+)-frontalin; The Grignard reagent is useful for many reactions

Packaging

5 mL in glass bottle

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993BF 3 / PGII
WGK Germany 
3
Flash Point(F) 
55.4 °F
Flash Point(C) 
13 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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