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233161 Aldrich

3′-(Trifluoromethyl)acetophenone

99%

Synonym: 3-Acetylbenzotrifluoride

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Properties

Related Categories Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Ketones,
InChI Key   ABXGMGUHGLQMAW-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.4611(lit.)
bp   198-200 °C(lit.)
density   1.235 g/mL at 25 °C(lit.)

Description

Packaging

5, 25 g in glass bottle

Application

3′-(Trifluoromethyl)acetophenone has been used in a key step during the preparation of a commercial fungicide.

General description

Asymmetric catalytic addition of ethyl groups to 3′-(trifluoromethyl)acetophenone catalyzed by ligands derived from trans-1,2-diaminocyclohexane and camphor sulfonyl chloride has been reported. Phenylation of 3′-(trifluoromethyl)acetophenone in the presence of dihydroxy bis(sulfonamide) ligand (enantioselective catalyst), titanium tetraisopropoxide and diphenylzinc has been investigated.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
1
Flash Point(F) 
174.2 °F
Flash Point(C) 
79 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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