Triisopropylsilane
99%
DOWNLOAD MSDS (PDF)-
CAS Number 6485-79-6
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Linear Formula [(CH3)2CH]3SiH
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Molecular Weight 158.36
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Beilstein Registry Number 1733718
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MDL number MFCD00009657
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PubChem Substance ID 24854011
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Popular Documents: Specification Sheet (PDF) | FTNMR (PDF)
Properties
| Related Categories | Chemical Synthesis, Organometallic Reagents, Organosilicon, Others, Reduction, |
| assay | 99% |
| refractive index |
n |
| bp | 84-86 °C/35 mmHg(lit.) |
| density | 0.773 g/mL at 25 °C(lit.) |
Description
Application
The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers).
Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.1
Packaging
10 g in glass bottle
50, 250 g in Sure/Seal™
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