|Related Categories||Chemical Synthesis, Organometallic Reagents, Organosilicon, Others, Reduction,|
|bp||84-86 °C/35 mmHg(lit.)|
|density||0.773 g/mL at 25 °C(lit.)|
The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers).
Used in a highly diastereoelective preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbene complex.1
10, 50, 250 g in Sure/Seal™
Certificate of Analysis
Certificate of Origin
|Precautionary statements||P261-P305 + P351 + P338|
|Personal Protective Equipment||Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter|
|Hazard Codes (Europe)||Xi|
|Risk Statements (Europe)||10-36/37/38|
|Safety Statements (Europe)||26-36|
|RIDADR||UN 1993C 3 / PGIII|
|Flash Point(F)||100.4 °F|
|Flash Point(C)||38 °C|
Tetrahedron Asymmetry 14, 3243-3247, (2003)
Tetrahedron Lett. 44, 7837-7840, (2003)
Aldrich MSDS 1, 1778:D / Corp MSDS 1 (2), 3471:A / FT-IR 1 (2), 1098:D / FT-IR 2 (3), 4339:B / FT-NMR 1 (3), 630:B / NMR-Reference 2 (2), 986:C / RegBook 1 (2), 2951:E / Structure Index 1, 467:B:2 / Vapor Phase 3, 1622:D
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