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235962 Aldrich

Trichloromethanesulfonyl chloride

97%

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds More...
InChI Key   ZCPSWAFANXCCOT-UHFFFAOYSA-N
assay   97%
mp   137-140 °C(lit.)

Description

Packaging

5 g in glass bottle

General description

Trichloromethanesulfonyl chloride is an efficient free radical chlorinating agent. It reacts with pent-4-enylcobaloximes in inert solvent under tugsten lamp irradiation to yield 2-(β,β,β- trichloroethyl)sulfolanes. It also reacts with trimethylsilyl enol ethers of acetophenones in the presence of a ruthenium (II) phosphine complex to yield 1-aryl-3,3-dichloropropen-1-one and α-chloroacetophenones.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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