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238198 Aldrich

Dimethyl maleate

96%

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Properties

Related Categories Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters,
InChI Key   LDCRTTXIJACKKU-ARJAWSKDSA-N
assay   96%
impurities   ≤4% dimethyl fumarate
refractive index   n20/D 1.441(lit.)
bp   204-205 °C(lit.)
solubility   water: soluble77.9 g/L at 20 °C
density   1.152 g/mL at 25 °C(lit.)

Description

Packaging

1 kg in glass bottle

100 g in glass bottle

General description

Dimethyl maleate (DMM) is a reactive dienophile and undergoes ultrasonic irradiation promoted Diels-Alder reaction with substituted furans. Mesoporous siliceous SBA-15-supported Cu catalyzed gas phase hydrogenolysis of DMM to 1,4-butanediol (BDO) has been reported. Aluminium chloride has been reported to accelerate the Diels-Alder reaction of DMM and anthracene. DMM can be synthesized by the esterification of maleic anhydride with sulfuric acid and methanol.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Target organs 
Skin
RIDADR 
NONH for all modes of transport
WGK Germany 
1
RTECS 
EM6300000
Flash Point(F) 
203 °F
Flash Point(C) 
95 °C
Protocols & Articles

Articles

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. Since the reaction involves the formation of a cyclic product vi...
Keywords: Addition reactions, Asymmetric synthesis, Building blocks, Catalysis, Cycloadditions, Diels-Alder reaction, Immobilization

Peer-Reviewed Papers
15

References

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