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238295 Aldrich

1-Iodooctane

98%

Synonym: Octyl iodide

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Properties

Related Categories Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
assay   98%
contains   copper as stabilizer
refractive index   n20/D 1.4878(lit.)
bp   225-226 °C(lit.)
mp   −46-−45 °C(lit.)
density   1.33 g/mL at 25 °C(lit.)

Description

Packaging

25, 100 g in glass bottle

General description

1-Iodooctane undergoes catalytic reduction by nickel (I) salen electrogenerated at a glassy carbon cathode in dimethylformamide1. Radical mechanism of formation of monolayer on silicon ground in the presence of 1-iodooctane has been studied by X-ray photoelectron spectroscopy2.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
Xi
Risk Statements (Europe) 
Safety Statements (Europe) 
26-36
WGK Germany 
3
RTECS 
RG9700100
Flash Point(F) 
188.6 °F
Flash Point(C) 
87 °C

Protocols & Articles

Peer-Reviewed Papers

References

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1. Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen. Raess PW, et al. J. Electroanal. Chem. 603(1), 124-34, (2007)

2. Evidence for a radical mechanism in monolayer formation on silicon ground (or scribed) in the presence of alkyl halides. Jiang G, et al. Langmuir 20(5), 17772-4, (2004)

Beil. 1,IV,425

Aldrich MSDS 1, 1101:B / Corp MSDS 1 (1), 2004:C / FT-IR 1 (1), 60:B / FT-IR 2 (1), 88:D / FT-NMR 1 (1), 88:C / NMR-Reference 2 (1), 63:D / RegBook 1 (1), 61:D / Structure Index 1, 7:A:7 / Vapor Phase 3, 88:A

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