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242934

Ethyl iodoacetate

98%

Synonym(s):

Ethyl 2-iodoacetate, Ethyl monoiodoacetate, Iodoacetic acid ethyl ester

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$151.30

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About This Item

Linear Formula:
ICH2COOC2H5
CAS Number:
623-48-3
Molecular Weight:
214.00
Beilstein/REAXYS Number:
741934
EC Number:
210-796-3
MDL number:
MFCD00001081
UNSPSC Code:
12352100
PubChem Substance ID:
24854592
NACRES:
NA.22

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Quality Level

200

assay

98%

refractive index

n20/D 1.503 (lit.)

bp

179-180 °C (lit.)

density

1.808 g/mL at 25 °C (lit.)

functional group

ester
iodo

storage temp.

2-8°C

SMILES string

CCOC(=O)CI

InChI

1S/C4H7IO2/c1-2-7-4(6)3-5/h2-3H2,1H3

InChI key

MFFXVVHUKRKXCI-UHFFFAOYSA-N

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295795290920528315
Ethyl iodoacetate 98%

Sigma-Aldrich

242934

Ethyl iodoacetate

Ethyl bromodifluoroacetate 98%

Sigma-Aldrich

295795

Ethyl bromodifluoroacetate

Ethyl pentafluoropropionate 98%

Sigma-Aldrich

290920

Ethyl pentafluoropropionate

2-Methyl-N-ethyl-N-(2-cyanoethyl)-4-aminobenzaldehyde 98%

Sigma-Aldrich

528315

2-Methyl-N-ethyl-N-(2-cyanoethyl)-4-aminobenzaldehyde

assay

98%

assay

98%

assay

98%

assay

98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

2-8°C

density

1.808 g/mL at 25 °C (lit.)

density

1.583 g/mL at 25 °C (lit.)

density

1.299 g/mL at 25 °C (lit.)

density

-

refractive index

n20/D 1.503 (lit.)

refractive index

n20/D 1.387 (lit.)

refractive index

n20/D 1.301 (lit.)

refractive index

-

bp

179-180 °C (lit.)

bp

112 °C/700 mmHg (lit.)

bp

75-76 °C (lit.)

bp

-

General description

Ethyl iodoacetate, also known as iodoacetic acid ethyl ester, serves as an alkylating agent and a radical precursor in organic synthesis. It is also commonly used as a lachrymatory agent. [1]

Application

Ethyl iodoacetate was used in the synthesis of trans-2,3-disubstituted indolines by reacting with 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade[2].

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

hcodes

H300,H314

Hazard Classifications

Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN4580
BCCF4174
BCBV8471
BCBL8657V
BCBG0849V

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François Brucelle et al.
The Journal of organic chemistry, 78(12), 6245-6252 (2013-06-01)
The preparation of trans-2,3-disubstituted indolines from 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade using ethyl iodoacetate and triethylborane is described. Further lactamization afforded substituted benzopyrrolizidinones with excellent diastereomeric ratios. The radical cascade/lactamization sequence was efficiently applied to the synthesis of

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