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249491 Aldrich

Tris(4-chlorophenyl)phosphine

95%

Synonym: NSC 136459, Tris(p-chlorophenyl)phosphine

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Properties

Related Categories Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds,
InChI Key   IQKSLJOIKWOGIZ-UHFFFAOYSA-N
assay   95%
mp   100-103 °C(lit.)

Description

Packaging

1 g in glass bottle

Application

Catalyst for:
• Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
• Solvent-free Heck reactions

Cocatalyst in:
• Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
• Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
• Rhodium-catalyzed hydrogenation reactions
• Platinum-catalyzed allylation reactions

Price and Availability


KitAlysis - Increasing Catalysis Productivity

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Additional Phosphines from Sigma-Aldrich

Sigma-Aldrich offers an extended variety of phosphines utilized in C-C bond forming processes. Recent work reported by Prof. Gregory Fu and coworkers has expanded the utility of trialkylphosphines an...
ChemFiles Volume 4 Article 2
Keywords: C-C bond formation

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