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250376 Aldrich

4-Formylmorpholine

99%

Synonym: 4-Morpholinecarboxaldehyde

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Properties

Related Categories Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines More...
InChI Key   LCEDQNDDFOCWGG-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.485(lit.)
bp   236-237 °C(lit.)
mp   20-23 °C(lit.)
density   1.145 g/mL at 25 °C(lit.)

Description

Packaging

100, 500 g in poly bottle

Application

4-Formylmorpholine has been used in the preparation of:
• adenine hydrochloride labelled with 14C
• terphenyl dialdehyde

General description

Treatment of 4-formylmorpholine with sulphur tetrafluoride in the presence of potassium fluoride gives 4-(trifluoromethyl)morpholine in excellent yields. 4-Formylmorpholine reacts with series of 2-alkyl-2-cyclohexen-1-ones in the presence of POCl3 to give the corresponding 3-alkyl-2-chloro-5,6-dihydrobenzaldehydes and allylic alcohols (by-product).

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
RTECS 
QD9694000
Flash Point(F) 
257 °F
Flash Point(C) 
125 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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