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251496 Aldrich

(−)-Isopinocampheylborane TMEDA complex

Synonym: (−)-N,N′-Bis(monoisopinocampheylborane)-N,N,N′,N′-tetramethylethylenediamine, (R)-Alpine-Boramine

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Reduction
InChI Key   QNDCJVKDHWRHGS-NCHGFZPDSA-N
mp   139-141 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Chiral hydroboration reagent.This amine-borane complex has been used as a polarity-reversal catalyst for the kinetic resolution of racemic esters and ketones.

Legal Information

Alpine-Boramine is a trademark of Sigma-Aldrich Co. LLC

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 2813 4.3 / PGIII
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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