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255068 Aldrich

Tris(methylthio)methane

98%

Synonym: Trimethyl trithioorthoformate

  • CAS Number 5418-86-0

  • Linear Formula (CH3S)3CH

  • Molecular Weight 154.32

  •  Beilstein Registry Number 1733825

  •  MDL number MFCD00009851

  •  PubChem Substance ID 24855282

  • Popular Documents:  FTNMR (PDF)  

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Properties

Related Categories Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfides/Disulfides, Sulfur Compounds More...
InChI Key   YFMZQCCTZUJXEB-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.577(lit.)
bp   102 °C/15 mmHg(lit.)
  225-227 °C(lit.)
mp   16 °C(lit.)
density   1.16 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

Application

Tris(methylthio)methane has been used in synthesis of:
• (−)-nephrosteranic acid and (−)-roccellaric acid
• (4R,5R)-5-({[1-(tert-butyl)-1,1-diphenylsilyl]oxy}methyl)4-[tri(methylthio)methyl]tetrahydro-furan-2-one
• terminal difluoromethylenes

General description

Tris(methylthio)methane is a carboxylic anion equivalent.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 3334
WGK Germany 
3
Flash Point(F) 
186.8 °F
Flash Point(C) 
86 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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