Synonym: DEZ, DEZn, Et2Zn, Zincdiethyl
|Related Categories||CVD and ALD Precursors by Metal, Chemical Synthesis, Dialkylzincs, Materials Science, Micro/NanoElectronics,|
|composition||Zn, 52.0 wt. % ((minimum))|
|density||1.205 g/mL at 25 °C(lit.)|
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100 g in Sure-Pac™
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.
Certificate of Analysis
Certificate of Origin
|Symbol||GHS02, GHS05, GHS09|
|Precautionary statements||P210-P222-P223-P231 + P232-P370 + P378-P422|
|Supplemental Hazard Statements||Reacts violently with water.|
|Personal Protective Equipment||Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter|
|Hazard Codes (Europe)||F,C,N|
|Risk Statements (Europe)||14-17-34-50/53|
|Safety Statements (Europe)||16-43-60-61|
|RIDADR||UN 3394 4.2/PG 1|
Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations
Diethylzinc-mediated one-step stereoselective synthesis of alpha-fluoroacrylates from aldehydes and ketones. Two different pathways depending on the carbonyl partner. Lemonnier G, Zoute L, Dupas G, et al. J. Org. Chem. 74(11), 4124-31, (2009)
Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral beta-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system. Qiu L, Wang Q, Lin L, et al. Chirality 21(2), 316-23, (2009)
Diastereoselective nickel-catalyzed reductive aldol cyclizations using diethylzinc as the stoichiometric reductant: scope and mechanistic insight. Joensuu PM, Murray GJ, Fordyce EA, et al. J. Am. Chem. Soc. 130(23), 7328-38, (2008)
Efficient chirality switching in the addition of diethylzinc to aldehydes in the presence of simple chiral alpha-amino amides. Burguete MI, Collado M, Escorihuela J, et al. Angew. Chem. Int. Ed. Engl. 46(47), 9002-5, (2007)
Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters. Org. Lett. 8, 5405, (2006)
A green chemistry approach to a more efficient asymmetric catalyst: solvent-free and highly concentrated alkyl additions to ketones. Jeon SJ, Li H, and Walsh PJ J. Am. Chem. Soc. 127(47), 16416-25, (2005)
Chiral aminonaphthol-catalyzed enantioselective carbonyl addition of diethylzinc to aromatic aldehydes high-throughput screened by CD-HPLC analysis. Xu L, Shen X, Zhang C, et al. Chirality 17(8), 476-80, (2005)
Switching of enantioselectivity in the catalytic addition of diethylzinc to aldehydes by regioisomeric chiral 1,3-amino sulfonamide ligands. Hirose T, Sugawara K, and Kodama K J. Org. Chem. 76(13), 5413-28, (2011)
The synthesis of new oxazoline-containing bifunctional catalysts and their application in the addition of diethylzinc to aldehydes. Coeffard V, Müller-Bunz H, and Guiry PJ Org. Biomol. Chem. 7(8), 1723-34, (2009)
Probing the importance of the hemilabile site of bis(phosphine) monoxide ligands in the copper-catalyzed addition of diethylzinc to N-phosphinoylimines: discovery of new effective chiral ligands. I. Bonnaventure and A. B. Charette, J. Org. Chem. 73, 6330-6340, (2008)
Fieser 1,253 / Fieser 2,134 / Fieser 3,257 / Fieser 4,153 / Fieser 5,219 / Fieser 6,194 / Fieser 11,182 / Fieser 17,115
Corp MSDS 1 (1), 1229:C / RegBook 1 (2), 3043:F / Sax 6, 1031 / Structure Index 1, 481:E:7
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