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257044 Aldrich

L-Selectride® solution

1.0 M lithium tri-sec-butylborohydride in THF

Synonym: Lithium tri-sec-butylborohydride solution

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Properties

Related Categories Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   ACJKNTZKEFMEAK-UHFFFAOYSA-N
concentration   1.0 M lithium tri-sec-butylborohydride in THF
density   0.89 g/mL at 25 °C

Description

Packaging

1.8 L in Sure-Pac™

200 mL in Sure-Pac™

Application

• Reducing agent

Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters
• Diastereoselective reduction reactions
• Hydride reduction of the Danishefsky pyranones
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes
• Synthesis of alkanols by carbonylation reactions

Recommended products

Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.

Legal Information

Selectride is a registered trademark of Sigma-Aldrich Co. LLC

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 3394 4.3(4.2) / PGI
WGK Germany 
3
Flash Point(F) 
1.4 °F
Flash Point(C) 
-17 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Related Products

septum inlet adapter

Product #

Description

Add to Cart

Z118206 Angled septum-inlet adapter, brass, inlet I.D. 6 mm × 6 mm
Z118141 Straight septum-inlet adapter, inlet I.D. 6 mm, brass
Z118192 Straight septum-inlet adapter, inlet I.D. 13.9 mm, brass

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