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26235 Aldrich

2-(3-Chloropropyl)-1,3-dioxolane

≥97.0% (GC)

Synonym: 4-Chlorobutyraldehyde ethylene acetal

  • CAS Number 16686-11-6

  • Empirical Formula (Hill Notation) C6H11ClO2

  • Molecular Weight 150.60

  •  Beilstein Registry Number 1236588

  •  MDL number MFCD00043135

  •  PubChem Substance ID 24855875

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Properties

Related Categories Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds More...
InChI Key   ZBPUNVFDQXYNDY-UHFFFAOYSA-N
assay   ≥97.0% (GC)
refractive index   n20/D 1.453
bp   93-94 °C/12 mmHg(lit.)
density   1.142 g/mL at 20 °C(lit.)

Description

Other Notes

Masked γ-chlorobutyraldehyde, useful for the introduction of the 3-(1,3-dioxolan-2-yl)propyl moiety; Preparation and use of the corresponding phosphonate

Packaging

5, 25 mL in glass bottle

Application

2-(3-Chloropropyl)-1,3-dioxolane (2-(3′-chloropropyl)-1,3-dioxolane) is a masked γ-chlorobutyraldehyde and was used for the introduction of 3-(1,3-dioxolan-2-yl)propyl moiety. It was also used in the synthesis of:
• (±)-histrionicotoxin and (±)-histrionicotoxin 235A using a two-directional strategy
• 4-iodobutyraldehyde, 5-iodovaleraldehyde and 5-iodo-2-petanone
• corresponding phosphonate

Price and Availability

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
174.2 °F
Flash Point(C) 
79 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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