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271411 Aldrich

Allyltributylstannane

97%

Synonym: Allyltri-n-butyltin, Allyltributyltin, Tributyl-2-propenylstannane

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Properties

Related Categories Chemical Synthesis, Organometallic Reagents, Organotin, Organotins
InChI Key   YLGRTLMDMVAFNI-UHFFFAOYSA-N
assay   97%
refractive index   n20/D 1.486(lit.)
bp   88-92 °C/0.2 mmHg(lit.)
density   1.068 g/mL at 25 °C(lit.)

Description

Packaging

5, 25, 100 g in glass bottle

Application

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2788 6.1 / PGIII
WGK Germany 
3
Flash Point(F) 
217.4 °F
Flash Point(C) 
103 °C
Protocols & Articles

Articles

Reagents for C–C Bond Formation

Aldrich carries a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-...
ChemFiles Volume 1 Article 3
Keywords: Acylations, Alkylations

Peer-Reviewed Papers
15

References

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