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275891 Aldrich

Dichloro(1,5-cyclooctadiene)palladium(II)

99%

Synonym: PdCl2(cod)

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
InChI Key   RRHPTXZOMDSKRS-PHFPKPIQSA-L
assay   99%
mp   210 °C (dec.)(lit.)

Description

Application

Catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes , Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate , and methoxycarbonylation of iodobenzene.

Packaging

2 g in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Carreira DOLEFIN Ligands

For the past years, the Carreira group has been employing chiral [2.2.2]bicyclooctadienes derived from (R)- or (S)-carvone in Ir(I)-catalyzed kinetic resolution of allylic carbonates1 and Rh(I)-catal...
Aldrich ChemFiles 2006, 6.10, 4.
Keywords: Addition reactions, Asymmetric synthesis, Catalysis, Chemfiles, Infrared spectroscopy, Ligands, Methods

Peer-Reviewed Papers
15

References

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