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277053 Aldrich

(S)-(+)-2-(Methoxymethyl)pyrrolidine

99%

Synonym: O-Methyl-L-prolinol, SMP

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts
InChI Key   CHPRFKYDQRKRRK-LURJTMIESA-N
assay   99%
optical activity   [α]20/D +2.4°, c = 2 in benzene
refractive index   n20/D 1.4457(lit.)
bp   62 °C/40 mmHg(lit.)
density   0.933 g/mL at 25 °C(lit.)

Description

Packaging

5 g in glass bottle

500 mg in glass insert

Application

Chiral auxiliary for asymmetric synthesis of propargyl alcohols and 4-nitrocyclohexanones, and for asymmetric Michael additions to enones.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
113 °F
Flash Point(C) 
45 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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