• USA Home
  • 280429 - (Triphenylphosphoranylidene)acetonitrile

EMAIL THIS PAGE TO A FRIEND
280429 Aldrich

(Triphenylphosphoranylidene)acetonitrile

97%

Synonym: (Cyano)(triphenylphosphoranylidene)methane, (Cyanomethylene)triphenylphosphorane, Cyanomethyltriphenylphosphonium ylide, NSC 135204

Purchase

Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents More...
InChI Key   APISVOVOJVZIBA-UHFFFAOYSA-N
assay   97%
mp   189-195 °C(lit.)

Description

Application

Wittig reagent for the preparation of α,β, unsaturated nitriles from carbonyl compounds.

Reactant for
• Preparation of antitrypanosomal activity
• Direct Michael addition of alkenes
• Synthesis of 1,6-enynes
• Beta-umpolung addition of nucleophiles to activated disubstituted alkyl allenes
• Stereoselective analysis of β-homoproline derivatives
• Stereoselective olefination of N-sulfonyl imines
• Palladacycle mediated synthesis of cyano-functionalized chiral diphosphines
• Horner-Wadsworth-Emmons reactions

Packaging

5 g in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

Set your institution to view full text papers.
Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?