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281573 Aldrich

(S)-(−)-1-Amino-2-(methoxymethyl)pyrrolidine

95%

Synonym: SAMP

  • CAS Number 59983-39-0

  • Empirical Formula (Hill Notation) C6H14N2O

  • Molecular Weight 130.19

  •  Beilstein Registry Number 1523794

  •  MDL number MFCD00064485

  •  PubChem Substance ID 24856982

  • Popular Documents:  FTIR (PDF)  

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines More...
InChI Key   BWSIKGOGLDNQBZ-LURJTMIESA-N
assay   95%
optical activity   [α]20/D −79°, neat
optical purity   ee: 97% (GLC)
refractive index   n20/D 1.465(lit.)
bp   42 °C/1.8 mmHg(lit.)
density   0.97 g/mL at 25 °C(lit.)

Description

Packaging

1 g in ampule

Application

(S)-(-)-1-Amino-2-(methoxymethyl)pyrrolidine may be used as a chiral auxiliary in the asymmetric synthesis of (S)-2-ethylhexanoic acid and (S)-2-n-propyl-4-pentenoic acid. It can undergo 1,4-addition to (E)-alkenyl-cyclohexyl sulfonates in the presence of zinc bromide to form β-hydrazino-cyclohexyl sulfonates.

Undergoes condensation reactions with carbonyl compounds to produce hydrazones which are useful synthons in highly enantioselective syntheses.

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Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
161.6 °F
Flash Point(C) 
72 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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94791 SnapIT Ampule Opener, Regular, for 1-2ml, 5-10ml, 10-15ml ampoules
43917 SnapIT Ampule Opener, large, for 5-10ml, 10-15ml, 20-25ml ampoules

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