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295531 Aldrich

Methylamine

anhydrous, ≥98%

Synonym: Monomethylamine

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Properties

Related Categories Acids & Bases, Alternative Energy, Bases, Chemical Synthesis, Materials Science,
grade   anhydrous
vapor density   1.08 (20 °C, vs air)
vapor pressure   27 psi ( 20 °C)
assay   ≥98%
autoignition temp.   806 °F
expl. lim.   4.9-20.8 %
bp   -6.3 °C(lit.)
mp   -93 °C(lit.)
density   0.70 g/mL at 20 °C(lit.)

Description

Packaging

170 g in steel cylinder

Recommended products

Stainless steel control valves Z146951, Z187224 or either of stainless steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661 is recommended.

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
16-26-39
RIDADR 
UN 1061 2.1
WGK Germany 
2
RTECS 
PF6300000
Flash Point(F) 
<-20.2 °F
Flash Point(C) 
<-29 °C

Protocols & Articles

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Peer-Reviewed Papers

References

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Cavitand-functionalized SWCNTs for N-methylammonium detection. Dionisio M, Schnorr JM, Michaelis VK, et al. J. Am. Chem. Soc. 134(15), 6540-3, (2012)

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Natural bond orbital analysis in the ONETEP code: applications to large protein systems. Lee LP, Cole DJ, Payne MC, et al. J. Comput. Chem. 34(6), 429-44, (2013)

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Function of genetically encoded pyrrolysine in corrinoid-dependent methylamine methyltransferases. Krzycki JA Curr. Opin. Chem. Biol. 8(5), 484-91, (2004)

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Origin and nature of bond rotation barriers: a unified view. Liu S J. Phys. Chem. A 117(5), 962-5, (2013)

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Rapid and efficient access to secondary arylmethylamines. Fleury-Brégeot N, Raushel J, Sandrock DL, et al. Chemistry 18(31), 9564-70, (2012)

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Semicarbazide-sensitive amine oxidases: enzymes with quite a lot to do. O'Sullivan J, Unzeta M, Healy J, et al. Neurotoxicology 25(1-2), 303-15, (2004)

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750 MHz 1H and 1H-13C NMR spectroscopy of human blood plasma. Nicholson JK, Foxall PJ, Spraul M, et al. Anal. Chem. 67(5), 793-811, (1995)

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Peroxisomal catalase deficiency modulates yeast lifespan depending on growth conditions. Kawałek A, Lefevre SD, Veenhuis M, et al. Aging (Albany. NY.) 5(1), 67-83, (2013)

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Temperature dependence of fluid phase endocytosis coincides with membrane properties of pig platelets. Wolkers WF, Looper SA, Fontanilla RA, et al. Biochim. Biophys. Acta 1612(2), 154-63, (2003)

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1H and (13)C NMR spectroscopic analysis of human saliva. Silwood CJ, Lynch E, Claxson AW, et al. J. Dent. Res. 81(6), 422-7, (2002)

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Natural Bond Critical Point analysis: quantitative relationships between natural bond orbital-based and QTAIM-based topological descriptors of chemical bonding. Weinhold F J. Comput. Chem. 33(30), 2440-9, (2012)

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Detection of autosomal dominant polycystic kidney disease by NMR spectroscopic fingerprinting of urine. Gronwald W, Klein MS, Zeltner R, et al. Kidney Int. 79(11), 1244-53, (2011)

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Photoinduced proton-coupled electron transfer of hydrogen-bonded p-nitrophenylphenol-methylamine complex in solution. Ko C, Solis BH, Soudackov AV, et al. J. Phys. Chem. B 117(1), 316-25, (2013)

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Improvement of post-thaw sperm motility in poor quality human semen. Sawetawan C, Bruns ES, and Prins GS Fertil. Steril. 60(4), 706-10, (1993)

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Methylamine utilization via the N-methylglutamate pathway in Methylobacterium extorquens PA1 involves a novel flow of carbon through C1 assimilation and dissimilation pathways. Nayak DD and Marx CJ J. Bacteriol. 196(23), 4130-9, (2014)

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Density functional theory study on the interactions between Ni(n) (n = 1,..., 6) and methylamine or acetic acid. Wei F, Liu W, Lv G, et al. J. Nanosci. Nanotechnol. 13(6), 4223-7, (2013)

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[Purification and characteristics of methanol dehydrogenase of Methylobacterium nodulans rhizosphere phytosymbionts]. Kuznetsova TA, Beschastnyĭ AP, Ponomareva ON, et al. Prikl. Biokhim. Mikrobiol. 48(6), 606-11, (2012)

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Effect of oral creatine supplementation on urinary methylamine, formaldehyde, and formate. Poortmans JR, Kumps A, Duez P, et al. Med. Sci Sports Exerc. 37(10), 1717-20, (2005)

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Modelling the roles of MAO and SSAO in glucose transport. McDonald A, Tipton K, O'Sullivan J, et al. J. Neural Transm. Gen. Sect. 114(6), 783-6, (2007)

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Metabonomic analysis of the therapeutic effect of Zhibai Dihuang Pill in treatment of streptozotocin-induced diabetic nephropathy. Zhao L, Gao H, Zhao Y, et al. J. Ethnopharmacol. 142(3), 647-56, (2012)

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Exploring the properties of small molecule protein binding via molecular simulations: the TRSH-p53 core domain complex. Hofer TS and van Gunsteren WF Mol. Biosyst. 8(11), 2891-900, (2012)

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Solutions able to reproduce in vivo surface-structure changes in bioactive glass-ceramic A-W. Kokubo T, Kushitani H, Sakka S, et al. J. Biomed. Mater. Res. 24(6), 721-34, (1990)

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In vitro and in vivo antitumor activity of methotrexate conjugated to human serum albumin in human cancer cells. Wosikowski K, Biedermann E, Rattel B, et al. Clin. Cancer Res. 9(5), 1917-26, (2003)

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The ammonia transport, retention and futile cycling problem in cyanobacteria. Ritchie RJ Microb. Ecol. 65(1), 180-96, (2013)

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Odor compounds from different sources of landfill: characterization and source identification. Fang JJ, Yang N, Cen DY, et al. Waste Manag. 32(7), 1401-10, (2012)

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Elucidation of the role of the methylene-tetrahydromethanopterin dehydrogenase MtdA in the tetrahydromethanopterin-dependent oxidation pathway in Methylobacterium extorquens AM1. Martinez-Gomez NC, Nguyen S, and Lidstrom ME J. Bacteriol. 195(10), 2359-67, (2013)

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Water adsorption at two unsolvated peptides with a protonated lysine residue: from self-solvation to solvation. Chutia S, Rossi M, and Blum V J. Phys. Chem. B 116(51), 14788-804, (2012)

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Impact of surface steps and oxygen pre-coverage on the adsorption of methylamine on gold. Lewoczko AD and BelBruno JJ Phys. Chem. Chem. Phys. 15(13), 4707-14, (2013)

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Physiological and pathological implications of semicarbazide-sensitive amine oxidase. Yu PH, Wright S, Fan EH, et al. Biochim. Biophys. Acta 1647(1-2), 193-9, (2003)

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Formation of aliphatic amine precursors of N-nitrosodimethylamine after oral administration of choline and choline analogues in the rat. Zeisel SH, Gettner S, and Youssef M Food Chem. Toxicol. 27(1), 31-4, (1989)

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Extension of yeast chronological lifespan by methylamine. Kumar S, Lefevre SD, Veenhuis M, et al. PLoS ONE 7(11), e48982, (2012)

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Assay of plasma semicarbazide-sensitive amine oxidase and determination of its endogenous substrate methylamine by liquid chromatography. Li H, Luo W, Lin J, et al. J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 810(2), 277-82, (2004)

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Activation of trans geometry in bifunctional mononuclear platinum complexes by a non-bulky methylamine ligand. Frybortova M, Novakova O, Stepankova J, et al. J. Inorg. Biochem. 126, 46-54, (2013)

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Deamination of methylamine and angiopathy; toxicity of formaldehyde, oxidative stress and relevance to protein glycoxidation in diabetes. Yu PH J. Neural Transm. Suppl. 52, 201-16, (1998)

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Isolation of a bacteriocin-producing lactococcus lactis and application of its bacteriocin to manage spoilage bacteria in high-value marine fish under different storage temperatures. Sarika AR, Lipton AP, Aishwarya MS, et al. Appl. Biochem. Biotechnol. 167(5), 1280-9, (2012)

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Isolation and characterization of human nuclear and cytosolic multisynthetase complexes and the intracellular distribution of p43/EMAPII. Wolfe CL, Warrington JA, Davis S, et al. Protein Sci. 12(10), 2282-90, (2003)

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Comparison of protective media and freezing techniques for cryopreservation of human semen. Stanic P, Tandara M, Sonicki Z, et al. Eur. J. Obstet. Gynecol. Reprod. Biol. 91(1), 65-70, (2000)

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A micro trapping system coupled with a high performance liquid chromatography procedure for methylamine determination in both tissue and cigarette smoke. Zhang Y, Mao J, Yu PH, et al. Anal. Chim. Acta 752, 106-11, (2012)

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Purification and characterization of azurin from the methylamine-utilizing obligate methylotroph Methylobacillus flagellatus KT. Dinarieva TY, Trashin SA, Kahnt J, et al. Can. J. Microbiol. 58(4), 516-22, (2012)

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3-D-QSAR and docking studies on the neuronal choline transporter. Werner J Geldenhuys et al Bioorg. Med. Chem. Lett. 20, 4870-7, (2010)

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Functional modulation of vascular adhesion protein-1 by a novel splice variant. Kaitaniemi S, Grön K, Elovaara H, et al. PLoS ONE 8(1), e54151, (2013)

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Benzylamine antihyperglycemic effect is abolished by AOC3 gene invalidation in mice but not rescued by semicarbazide-sensitive amine oxidase expression under the control of aP2 promoter. Grès S, Bour S, Valet P, et al. J. Physiol. Biochem. 68(4), 651-62, (2012)

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Native and transformed alpha2-macroglobulin in plasma from patients with multiple sclerosis. Gunnarsson M, Sundström P, Stigbrand T, et al. Acta Neurol. Scand 108(1), 16-21, (2003)

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Pyrrolysyl-tRNA synthetase: an ordinary enzyme but an outstanding genetic code expansion tool. Wan W, Tharp JM, and Liu WR Biochim. Biophys. Acta 1844(6), 1059-70, (2014)

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A synthetic method to access symmetric and non-symmetric 2-(N,N'-disubstituted)guanidinebenzothiazoles. Cruz A, Padilla-Martínez II, and García-Báez EV Molecules 17(9), 10178-91, (2012)

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Glucose is a pH-dependent motor for sperm beat frequency during early activation. Mannowetz N, Wandernoth PM, and Wennemuth G PLoS ONE 7(7), e41030, (2012)

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Why is glycine not a part of the osmoticum in the urea-rich cells? Khan S, Bano Z, Singh LR, et al. Protein Pept. Lett. 20(1), 61-70, (2013)

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Methylamine: a new endogenous modulator of neuron firing? Pirisino R, Ghelardini C, De Siena G, et al. Med. Sci. Monit. 11(8), RA257-61, (2005)

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Lipopolysaccharide impairs hepatocyte ureagenesis from ammonia: involvement of mitochondrial aquaporin-8. Soria LR, Marrone J, Molinas SM, et al. FEBS Lett. 588(9), 1686-91, (2014)

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Merck 14,6014

Beil. 4,IV,118

Corp MSDS 1 (2), 2283:D / RegBook 1 (1), 301:A / Sax 6, 1795 / Structure Index 1, 41:A:1 / Vapor Phase 3, 363:D

RegBook 1 (1), 301:A

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