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29590 Aldrich

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

≥99.0% (C)

Synonym: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Crabtree’s catalyst, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex, [Ir(cod)(PCy3)(py)]PF6, [Ir(cod)(PCy3)(py)]PF6

  • CAS Number 64536-78-3

  • Empirical Formula (Hill Notation) C31H50F6IrNP2

  • Molecular Weight 804.89

  •  MDL number MFCD00075097

  •  PubChem Substance ID 57648382

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium More...
InChI Key   UJXHUUQZACSUOG-KJWGIZLLSA-N
assay   ≥99.0% (C)
mp   175 °C (dec.)(lit.)

Description

Other Notes

Catalyst for the homogeneous hydrogenation of olefins

Packaging

250 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Price and Availability


Laboratory Gloves

Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles

Articles

Robert Crabtree Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Robert Crabtree Group – Professor Product Portal
Keywords: Asymmetric synthesis, Hydrogenations

Peer-Reviewed Papers
15

References

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