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297976 Aldrich

Tributylborane solution

1.0 M in diethyl ether

Synonym: TBB, Tributylboron

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Properties

Related Categories Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
InChI Key   CMHHITPYCHHOGT-UHFFFAOYSA-N
concentration   1.0 M in diethyl ether
density   0.719 g/mL at 25 °C

Description

Packaging

100 mL in Sure/Seal™

Application

Reactant for:
• Addition reactions for synthesis of phenyltrialkylborate salts
• Boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines
• Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists
• Multicomponent C-alkylation reactions with aromatic aldimines
• One-pot alkylation-boration and electrophilic substitution

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
May form explosive peroxides.
RIDADR 
UN 1993A 3 / PGI
WGK Germany 
1
Flash Point(F) 
-40 °F
Flash Point(C) 
-40 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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