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302473 Aldrich

Chlorobis(cyclooctene)rhodium(I),dimer

98%

Synonym: [Rh(coe)2Cl]2

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium More...
InChI Key   GQPAPAIPOLEZHT-XFCUKONHSA-L
assay   98%
mp   190 °C (dec.)(lit.)

Description

Application

Precusor for rhodium(I) and used as a precatalyst in a variety of reactions including aryl- and vinyl-C-H bond activation, hydroiminoacylation, cycloisomerization, and C-C bond activation

Packaging

1 g in glass bottle

250 mg in glass bottle

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles

Articles

Direct Arylation of Heterocycles

Lewis and co-workers have recently disclosed a highly functional-group compatible Rh-catalyzed C-H bond activation for the rapid synthesis of functionalized heterocycles. The method relies on the use...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 8.
Keywords: Arylations, Catalysis, Chemfiles, Dehydrogenation, Hydrohalogenations, Ligands, Methods, Reductions

Peer-Reviewed Papers
15

References

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