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319716 Aldrich

(1R)-(+)-Camphorsulfonylimine

99%

Synonym: (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide, (7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide

  • CAS Number 107869-45-4

  • Empirical Formula (Hill Notation) C10H15NO2S

  • Molecular Weight 213.30

  •  Beilstein Registry Number 85297

  •  MDL number MFCD00064576

  •  PubChem Substance ID 24859182

  • Popular Documents:  FTNMR (PDF)  

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Sulfonimides/Sulfinimides More...
InChI Key   ZAHOEBNYVSWBBW-MHPPCMCBSA-N
assay   99%
optical activity   [α]20/D +34°, c = 1 in chloroform
mp   229-230 °C(lit.)

Description

Application

(R) and (S) forms are precursors to chiral (camphorsulfonyl)oxaziridines employed in the asymmetric hydroxylation of ester and amide enolates.

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Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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