• USA Home
  • 320188 - Boron trifluoride diethyl etherate

EMAIL THIS PAGE TO A FRIEND

320188 Aldrich

Boron trifluoride diethyl etherate

≥46% BF3 basis

Synonym: Boron trifluoride ethyl etherate

Purchase

Properties

Related Categories Acids, Acids & Bases, Boron, Catalysis and Inorganic Chemistry, Chemical Synthesis,
grade   for synthesis
vapor density   4.9 (vs air)
vapor pressure   4.2 mmHg ( 20 °C)
assay   ≥46% BF3 basis
expl. lim.   36 %
refractive index   n20/D 1.344(lit.)
bp   126-129 °C(lit.)
mp   −58 °C(lit.)
density   1.15 g/mL(lit.)

Description

Other Notes

This product has been replaced by 175501-ALDRICH | Boron trifluoride diethyl etherate for synthesis

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.





Customers Also Viewed

Boron trifluoride

≥99.5%

Boron trifluoride diethyl etherate

purified by redistillation, ≥46.5% BF3 basis

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 2604 3(8) / PGI
WGK Germany 
3
Flash Point(F) 
118.4 °F
Flash Point(C) 
48 °C

Protocols & Articles

Related Content

Molarity Calculator and Normality Calculator for Acids and Bases

The molarity calculator tool provides lab-ready directions describing how to prepare an acid or base solution of specified Molarity (M) or Normality (N) from a concentrated acid or base solution.  To...

Peer-Reviewed Papers

References

Set your institution to view full text papers.

Synthesis and antiproliferative activities of novel 5'-Schiff-base group substituted psoralen derivatives. Chen CY, Sun JG, Huang ZZ, et al. Yao Xue Xue Bao 46(1), 64-9, (2011)

Loading...


(1-Alkynyl)dicarbonylcyclopentadienyliron complexes as electron-rich alkynes in organic synthesis: BF3-mediated [2+2] cycloaddition/ring-opening providing (2-alkenyl-1-imino)iron complexes. Nakaya R, Yasuda S, Yorimitsu H, et al. Chemistry 17(31), 8559-61, (2011)

Loading...


C-H bond functionalization via hydride transfer: Lewis acid catalyzed alkylation reactions by direct intramolecular coupling of sp3 C-H bonds and reactive alkenyl oxocarbenium intermediates. McQuaid KM and Sames D J. Am. Chem. Soc. 131(2), 402-3, (2009)

Loading...


Stereoselective radical addition of an acetal to sterically tuned enantiomerically pure N-sulfinyl imines. Akindele T, Yamada K, Sejima T, et al. Chem. Pharm. Bull. 58(2), 265-9, (2010)

Loading...


One-pot synthesis of chemically modified vegetable oils. Sharma BK, Liu Z, Adhvaryu A, et al. J. Agric. Food Chem. 56(9), 3049-56, (2008)

Loading...


Stereoselective one-pot, three-component synthesis of 4-aryltetrahydropyran via Prins-Friedel-Crafts reaction. Reddy UC, Bondalapati S, and Saikia AK J. Org. Chem. 74(6), 2605-8, (2009)

Loading...


Novel halo-oxo-allenic fatty ester derivatives from epoxidized methyl santalbate (methyl trans-11-octadecen-9-ynoate). Lie Ken Jie MS, Lau MM, Lam CN, et al. Chem. Phys. Lipids 125(2), 93-101, (2003)

Loading...


Delocalized carotenoid cations in relation to the soliton model. Lutnaes BF, Kildahl-Andersen G, Krane J, et al. J. Am. Chem. Soc. 126(29), 8981-90, (2004)

Loading...


Stereochemical surprises in the Lewis acid-mediated allylation of isatins. Vyas DJ, Fröhlich R, and Oestreich M J. Org. Chem. 75(19), 6720-3, (2010)

Loading...


BF3-promoted synthesis of diarylhexahydrobenzo[f]isoquinoline. Chang MY, Lin CH, Chen YL, et al. Org. Lett. 12(6), 1176-9, (2010)

Loading...


The cephalostatins. 21. Synthesis of bis-steroidal pyrazine rhamnosides (1). Pettit GR, Mendonça RF, Knight JC, et al. J. Nat. Prod. 74(9), 1922-30, (2011)

Loading...


Synthesis and anti-inflammatory activity of N-phthalimidomethyl 2,3-dideoxy- and 2,3-unsaturated glycosides. Meng XB, Han D, Zhang SN, et al. Carbohydr. Res. 342(9), 1169-74, (2007)

Loading...


Unexpectedly convenient and stereoselective synthesis of 4α-acyloxy-2-chloropodophyllotoxins in the presence of BF₃ ·Et₂O. Xu H, Xiao X, Zhao XF, et al. Bioorg. Med. Chem. Lett. 21(13), 4008-12, (2011)

Loading...


Benzoylated ethyl 1-thioglycosides: direct preparation from per-O-benzoylated sugars Sail , D. and P. Kováč Carbohydr. Res., (2012)

Loading...


Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system. Ikeda K, Torisawa Y, Nishi T, et al. Bioorg. Med. Chem. 11(14), 3073-6, (2003)

Loading...


One-pot cross-coupling of N-acyl N,O-acetals with alpha,beta-unsaturated compounds. Xiang YG, Wang XW, Zheng X, et al. Chem. Commun. (Camb.) (45), 7045-7, (2009)

Loading...


Synthesis of oxabicyclo[3.3.1]nonenes and substituted tetrahydropyrans via (3,5)-oxonium-ene reaction. Saha P, Gogoi P, and Saikia AK Org. Biomol. Chem. 9(12), 4626-34, (2011)

Loading...


The O-acylation of ketone enolates by allyl 1H-imidazole-1-carboxylate mediated with boron trifluoride etherate: a convenient procedure for the synthesis of substituted allyl enol carbonates. Trost BM and Xu J J. Org. Chem. 72(24), 9372-5, (2007)

Loading...


BF₃·Et₂O-induced stereoselective aldol reaction with benzaldehyde, and steroid sapogenins and its application to a convenient synthesis of dinorcholanic lactones. Ruíz-Pérez KM, Romero-Ávila M, Tinajero-Delgado V, et al. Steroids 77(7), 819-28, (2012)

Loading...


Beta-anomeric selectivity in the glycosidation of D-mannofuranurono-6,3-lactone catalyzed by boron trifluoride diethyl etherate. Roussel M, Moutard S, Perly B, et al. Carbohydr. Res. 338(4), 375-8, (2003)

Loading...


Revisiting the aldol reaction of cis-α,β-epoxyaldehyde promoted by BF(3)·Et(2)O: direct access to 2-deoxy-2-fluoro heptulosonic ester analogues. Filali H, Danel M, Ballereau S, et al. Carbohydr. Res. 345(17), 2421-6, (2010)

Loading...


A synthesis of 3-phenyl-1,2,3,4-tetrahydroisoquinoline and 2-phenyl-1,2,4,5-tetrahydro-3H-3-benzazepine via Pummerer-type cyclization: enhancing effect of boron trifluoride diethyl etherate on the cyclization. Saitoh T, Ichikawa T, Horiguchi Y, et al. Chem. Pharm. Bull. 49(8), 979-84, (2001)

Loading...


Studies on the BF3·Et2O catalyzed Baeyer-Villiger reaction of spiroketalic steroidal ketones. Macias-Alonso M, Morzycki JW, and Iglesias-Arteaga MA Steroids 76(3), 317-23, (2011)

Loading...


Rapid conversion of spirostans into furostan skeletons at room temperature. Viñas-Bravo O, Martinez-Pascual R, Vega-Baez JL, et al. Steroids 77(1-2), 59-66, (2012)

Loading...


Reaction of mono-epoxidized conjugated linoleic acid ester with boron trifluoride etherate complex. Jie MS and Lam CN Lipids 39(6), 583-7, (2004)

Loading...


Merck 14,1350

Beil. 1,IV,1321

Fieser 1,70 / Fieser 2,35 / Fieser 3,33 / Fieser 4,44 / Fieser 5,52 / Fieser 6,65 / Fieser 7,31 / Fieser 8,51 / Fieser 9,64 / Fieser 10,52 / Fieser 11,72 / Fieser 12,66 / Fieser 13,43 / Fieser 14,54 / Fieser 15,45 / Fieser 16,44 / Fieser 17,52

Aldrich MSDS 1, 220:B / Corp MSDS 1 (1), 483:C / FT-IR 2 (3), 4468:B / FT-IR 1 (2), 1137:C / IR-Spectra (3), 1553:G / IR-Spectra (2), 1328:B / NMR-Reference 2 (2), 1015:D / RegBook 1 (2), 3031:J / Sax 6, 515 / Sigma FT-IR 1 (2), 1017:A / Structure Index 1, 479:A:9

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?